太平洋中部锰结核的稀土元素   总被引：5，自引：0，他引：5  

郭世勤  孙文泓 《地质学报》1992,66(2):135-147

太平洋中部CP区和CC区锰结核中含有丰富的稀土元素。CP区结核较CC区结核富含REE,海山区结核较平原丘陵区结核富含REE。结核内部REE呈带状分布。结核和沉积物的稀土分布模式相同,与海水的模式曲线为镜像关系。三价稀土元素自海水进入结核时没有产生明显分异。造成结核和沉积物中REE丰度差别的主要原因是氧化还原条件。太平洋地区洋底的氧化还原强度主要受南极底流控制。结核中含铁相是REE的主要富集场所。  相似文献   

土壤铁锰结核中锰矿物类型鉴定的探讨   总被引：5，自引：1，他引：4  

谭文峰  刘凡  李永华  贺纪正  李学垣 《矿物学报》2000,20(1):63-67

用化学选择溶提、X射线衍射 (XRD)等技术 ,对土壤铁锰结核中锰矿物类型的鉴定进行了探讨。结果表明 :根据 0 .1mol·L-1盐酸羟胺 (HAHC)处理前后土壤铁锰结核的XRD峰的变化 ,可鉴定出其所含的锂硬锰矿和钙锰矿 ;分析HAHC处理前后同一XRD谱线上不受锰矿物干扰的相邻层状硅酸盐矿物衍射峰与所含锰矿物衍射峰强度的比值变化 ,确定了水钠锰矿的存在 ;结合铁锰结核中与锰矿物类型相关的元素含量 ,可鉴定出其所含的钡硬锰矿和铅锰矿。  相似文献   

A Preliminary Study on the Preparation of Four Pacific Ocean Polymetallic Nodule and Sediment Reference Materials: GSPN-2, GSPN-3, GSMS-2 and GSMS-3   总被引：6，自引：0，他引：6  

Yimin Wang  Daihong Luo  Yushu Gao  Haowei Song  Jiaxi Li  Weiyue Chen  Yunye Teng  Shiguang Zhou 《Geostandards and Geoanalytical Research》1998,22(2):247-254

The research project for the preparation of two polymetallic nodule (GSPN-2, GSPN-3) and two marine sediment (GSMS-2, GSMS-3) reference materials was completed in 1996. The samples were collected from the Eastern and Central Pacific Ocean and prepared to less than 74 μm fine powder. The homogeneity of the materials was tested by X-ray fluorescence spectrometry. The relative standard deviations (RSD %) of measurements of selected elements in samples taken from thirty bottles selected at random were less than 0.5%. Thirty four laboratories worldwide participated in the collaborative analysis programme. The number of elements or constituents analysed was seventy nine for nodules and eighty one for sediments. Among those, sixty three elements were certified in each sample. The sum of major elements or components is 99.7% for GSPN-2, 99.5% for GSPN-3, 99.8% for GSMS-2 and 99.8% for GSMS-3.  相似文献   

Emplacement of xenolith nodules in the Kaupulehu lava flow,Hualalai Volcano,Hawaii     

J. E. Guest  P. D. Spudis  R. Greeley  G. J. Taylor  S. M. Baloga 《Bulletin of Volcanology》1995,57(3):179-184

The basaltic Kaupulehu 1800–1801 lava flow of Hualalai Volcano, Hawaii contains abundant ultramafix xenoliths. Many of these xenoliths occur as bedded layers of semi-rounded nodules, each thinly coated with a veneer (typically 1 mm thick) of lava. The nodule beds are analogous to cobble deposits of fluvial sedimentary systems. Although several mechanisms have been proposed for the formation of the nodule beds, it was found that, at more than one locality, the nodule beds are overbank levee deposits. The geological occurrence of the nodules, certain diagnostic aspects of the flow morphology and consideration of the inferred emplacement process indicate that the Kaupulehu flow had an exceptionally low viscosity on eruption and that the flow of the lava stream was extremely rapid, with flow velocities of at least 10 m s^-1 (more than 40 km h^-1). This flow is the youngest on Hualalai Volcano and future eruptions of a similar type would pose considerable hazard to life as well as property.  相似文献   

多金属结核海底照片的图象识别与处理   总被引：1，自引：1，他引：1  

王公念  朱克超  叶剑平  许洪泉  梁朴 《地质论评》1996,42(6):560-563

NIRS是结核海底照片的处理系统。照片具点光源特征,中间亮边部暗,依光强与射线距离平方成反比的关系将其校正为平行光源照片;模式识别综合利用灰度、形状等特征分割图象与背景,圈定结核,然后计算覆盖率、估算丰度,以数据库存储管理信息。配置了1850DPI底片扫描仪,显示图象清晰。分析了DY851,DY853航次照片处理结果,划分出五种照片类型,提出了系统的最佳使用方法,讨论了照片处理质量的评价方法。  相似文献   

An Evaluation of the Inter‐Method Discrepancies in Ferromanganese Nodule Proficiency Test GeoPT 23A     

Cornelia Kriete 《Geostandards and Geoanalytical Research》2011,35(3):319-340

Round 23 of the GeoPT international proficiency testing scheme included the ferromanganese nodule powder FeMn‐1 which was distributed as an additional sample (23A). The aim of this initiative was to assess overall analytical performance for such a challenging oxide matrix with a view to the possible certification of such a material in accordance with ISO Guide requirements. To investigate inter‐method discrepancies, precision data and the method means for the most frequently used analytical methods (XRF, ICP‐MS and ICP‐AES) and sample preparation techniques were calculated and then compared using statistical tests of equivalence. For most major elements, XRF and ICP‐AES data dominated and these were found to give equivalent results. In contrast, for most trace elements significant discrepancies were detected between data obtained by different analytical methods. Possible causes are discussed with a view to attributing their origin to calibration strategy, sensitivity or interferences. It is assumed that the unusual oxide matrix generated unexpected interferences and thus method bias. Discrepancies observed between data from different analytical methods provide valuable information for the participating analysts, helping them to avoid systematic errors and thus minimising bias. They also suggest actions necessary to improve results for any future certification of such a material.  相似文献   

钙锰矿的研究进展     

崔浩杰  冯雄汉  刘凡  谭文峰  邱国红  陈秀华 《地球科学进展》2009,24(10):1084-1093

钙锰矿是土壤、沉积物及海洋锰结核中常见的以3×3结构为主的一族大隧道构造氧化锰矿物.隧道中存在水分子和阳离子,形貌以片状、针状或纤维状为主.水钠锰矿→布塞尔矿→钙锰矿的转化是钙锰矿形成的一个重要途径.这种转化在常压条件下受体系温度、pH、共存粘土矿物、转化时间以及前驱物布塞尔矿亚结构特点,如层间交换离子类型、浓度、以水合离子形态或与MnO6八面体空穴上方键合的强弱、结晶度、Mn(Ⅲ)的含量与迁移特点等因素影响.钙锰矿独特的结构使其所具有的离子吸附、氧化与催化特性及分子级的隧道空间等有望作为特异的分子筛、二次电池正极材料、有机反应催化荆等在环境科学和材料科学等领域具有广阔的应用前景.  相似文献   

深海扬矿系统中颗粒过泵回流试验研究     

王英杰  阳宁  金星 《海洋工程》2012,30(2):100-104

两相流过泵回流试验是模拟水力提升系统紧急停泵情况下垂直管道中颗粒运动状态,紧急停泵时,可能会出现堵管、难于输送等现象。为提高管道水力输送安全性,采用三种不同的模拟结核颗粒(粒径分别为d≤10 mm,d≤20 mm,d≤50 mm),两种不同浓度(CV=5%,CV=8%),在两级泵额定流量Q=420 m3/h条件下进行了过泵回流试验,分析了试验结果,从多个方面总结了堵管原因。认为实际工程中应该严格控制颗粒上限粒径,采用合适的颗粒级配,并对管道定期进行清洗,尽量减少管道的大角度转弯和断面突变。  相似文献   

黄土碳酸盐碳同位素环境意义讨论          下载免费PDF全文

金雅琪  苗甜  路珂珂  杨雁鹏  粱孔秋  陈忠  宋垠先 《盐湖研究》2021,29(1)

黄土碳酸盐碳同位素广泛应用于第四纪气候环境变化的研究中,以往的大多数研究中无论是利用钙结核、次生碳酸盐还是成壤碳酸盐,认为其反映了C4植物的丰度。黄土高原碳酸盐碳同位素表现为黄土层高,古土壤层中低,即黄土层中C4植物丰度高于古土壤层。然而,这样的结果和黄土有机碳同位素得到的结果矛盾,有机碳同位素的结果表明温度对C4植物的分布起到了决定性作用。由于有机碳同位素对植物类型的反映更为直接而可靠,因此碳酸盐碳同位素反映C4植物丰度存在疑问。对黄土高原黄土碳酸盐碳同位素的系统概括后认为,第四纪期间黄土碳酸盐碳同位素与C4植物有直接联系,但C4植物丰度不是唯一决定性的因素,碳酸盐碳同位素的指示意义存在复杂性。在黄土高原地区,植被发育程度、与大气CO2交换程度、植被本身的碳同位素值的变化以及原生碳酸盐的影响等因素都会对碳酸盐碳同位素产生影响。由黄土碳酸盐碳同位素的讨论可延伸到不同土壤碳酸盐碳同位素揭示的环境指示意义,不同的土壤环境,其气候条件、植被类型及发育程度、大气CO2的交换情况、微生物的活动及土壤次生碳酸盐受原生碳酸盐溶解的影响等因素都会对碳同位素产生不同程度影响,哪种或哪几种因素产生主要作用,在不同区域土壤环境中是不一样的。具体研究中需确定影响的核心因素,才能确定碳同位素的环境指示意义。  相似文献   

黎塘岩溶区土壤铁锰结核的地球化学特征研究   总被引：8，自引：2，他引：6  

苏春田  唐健生  单海平  陈宏峰  夏日元  邹胜章 《中国岩溶》2008,27(1):43-49

对黎塘岩溶区土壤铁锰结核的地球化学特征研究表明:与土壤相比,铁锰结核的化学组成中仍以SiO2、Al2O3和Fe2O3为主,但Fe2O3的含量明显增加,成为铁锰结核中含量最多的氧化物,MnO含量也有一定程度增加,它们富集系数分别为5．19和3．40;铁锰结核对重金属具有明显的富集效应,其富集顺序为Cr（M）〉Pb〉Co〉Zn〉Ni〉Ba〉Li,它在土壤中的含量受成土母质及浅层地下水活动的影响。元素的相关分析及因子分析表明,铁锰结核在形成过程中还具有成核富集效应、专性吸附效应和成核易淋溶效应。   相似文献